The other answer is correct and summed it up nicely: we are 95% confident the accuracy value will fall somewhere between .666 and .864. It is a probability claim for how representative your number is.
To your other question, it could mean a couple different things based on your data what the CI means. In general, the larger the CI, the bigger the range for your numbers will be. For example, we can be 95% certain the accuracy falls between .666 and .864, but you may change the CI to 99% and it might give you a value like .333 and 1.264 or something.
When you have a large range in your CI, it usually means you have high variability in your data (some of your datapoints are around .666 while others are around .864). The more data you have and the more related the data is, the lower the range will become.
It depends for what purpose you are crunching these numbers for, but generally speaking, Higher confidence intervals like 95% give you more certainty in the data while a smaller confidence interval like 75% can compile more neatly digestible graphs while sacrificing some accuracy.
Hope this helps a bit! :)